Table T14. Precision (reproducibility) of ICP-AES analyses on the JY-2000, Expedition 312.
Standard: |
BAS-140 (N = 12) | BAS-148 (N = 13) | BAS-206 (N = 13) | BAS-312 (N = 12) | ||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
Average | Standard deviation |
RSD (%) |
Average | Standard deviation |
RSD (%) |
Average | Standard deviation |
RSD (%) |
Average | Standard deviation |
RSD (%) |
|
Major element oxide (wt%): | ||||||||||||
SiO2 | 50.85 | 0.33 | 0.66 | 50.09 | 0.32 | 0.63 | 49.35 | 0.27 | 0.54 | 49.86 | 0.35 | 0.70 |
TiO2 | 1.00 | 0.01 | 1.19 | 0.90 | 0.01 | 1.36 | 2.09 | 0.04 | 1.71 | 1.33 | 0.02 | 1.62 |
Al2O3 | 14.34 | 0.08 | 0.55 | 15.55 | 0.08 | 0.50 | 13.87 | 0.05 | 0.33 | 15.41 | 0.10 | 0.63 |
Fe2O3 | 11.19 | 0.09 | 0.77 | 9.98 | 0.05 | 0.55 | 14.58 | 0.09 | 0.62 | 10.77 | 0.06 | 0.53 |
MnO | 0.19 | 0.00 | 0.82 | 0.17 | 0.00 | 1.06 | 0.26 | 0.00 | 0.16 | 0.18 | 0.00 | 1.19 |
MgO | 8.18 | 0.05 | 0.66 | 8.63 | 0.05 | 0.61 | 6.73 | 0.05 | 0.67 | 7.79 | 0.05 | 0.63 |
CaO | 12.51 | 0.11 | 0.91 | 12.88 | 0.09 | 0.72 | 9.92 | 0.03 | 0.34 | 11.89 | 0.10 | 0.88 |
Na2O | 1.80 | 0.02 | 1.10 | 2.05 | 0.01 | 0.58 | 2.83 | 0.02 | 0.79 | 2.44 | 0.03 | 1.22 |
K2O | 0.01 | 0.00 | 18.78 | 0.05 | 0.00 | 3.64 | 0.18 | 0.00 | 1.23 | 0.06 | 0.00 | 4.11 |
P2O5 | 0.08 | 0.05 | 61.20 | 0.07 | 0.03 | 49.18 | 0.19 | 0.02 | 12.08 | 0.09 | 0.03 | 27.93 |
Totals: | 100.12 | 0.36 | 0.36 | 100.37 | 0.44 | 0.44 | 100.00 | 0.28 | 0.28 | 99.83 | 0.44 | 0.45 |
Trace element (ppm): | ||||||||||||
Ba | BDL | — | — | BDL | — | — | 42.75 | 1.04 | 2.44 | 9.54 | 0.28 | 2.96 |
Sr | 41.50 | 1.02 | 2.47 | 58.22 | 0.47 | 0.81 | 99.16 | 0.61 | 0.61 | 98.85 | 1.19 | 1.20 |
Zr | 45.85 | 0.61 | 1.34 | 44.62 | 0.52 | 1.17 | 111.19 | 1.02 | 0.92 | 71.43 | 0.86 | 1.20 |
Y | 23.88 | 0.22 | 0.92 | 22.33 | 0.13 | 0.58 | 34.14 | 0.05 | 0.14 | 24.65 | 0.22 | 0.91 |
Sc | 40.17 | 0.37 | 0.91 | 39.40 | 0.42 | 1.05 | 42.59 | 0.49 | 1.15 | 39.99 | 0.34 | 0.85 |
V | 307.58 | 2.12 | 0.69 | 264.40 | 2.21 | 0.84 | 421.96 | 3.29 | 0.78 | 295.38 | 2.07 | 0.70 |
Cr | 191.81 | 1.99 | 1.04 | 381.61 | 6.88 | 1.80 | 73.28 | 1.12 | 1.54 | 259.03 | 2.77 | 1.07 |
Co | 46.31 | 2.59 | 5.59 | 44.88 | 1.47 | 3.28 | 50.78 | 1.05 | 2.07 | 44.27 | 1.71 | 3.85 |
Ni | 83.85 | 3.53 | 4.21 | 116.43 | 2.40 | 2.06 | 45.50 | 1.53 | 3.35 | 88.12 | 3.27 | 3.71 |
Cu | 67.50 | 1.07 | 1.58 | 75.35 | 1.14 | 1.51 | 52.73 | 1.44 | 2.73 | 74.32 | 1.07 | 1.44 |
Zn | 78.57 | 2.00 | 2.54 | 74.30 | 3.86 | 5.20 | 99.29 | 3.38 | 3.41 | 82.75 | 1.41 | 1.71 |
Notes: Relative standard deviation (RSD) is calculated as the standard deviation of N analyses divided by the average value. BDL = below detection limit, — = not applicable.
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