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The authors thank Rita Fröhlking and Susanne Wiebe (both Alfred Wegener Institute, Bremerhaven) for help with the XRD analyses and Thierry Adatte, Mitch Malone, and editor Lorri Peters for their careful review of the manuscript. This research used samples and/or data provided by the Integrated Ocean Drilling Program (IODP). This research was funded by grant BO 1049/8 of the Deutsche Forschungsgemeinschaft. This is RCOM publication number 0540.