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Table T6. Handheld X-ray fluorescence measurements for four certified silicate standards, Expedition 345.
|
BCR-2
|
BHVO-2
|
JB-2
|
JA-1
|
Compiled values
|
Measured (N = 5)
|
Accuracy (%)
|
Precision (%)
|
Compiled values
|
Measured (N = 5)
|
Accuracy (%)
|
Precision (%)
|
Compiled values
|
Measured (N = 5)
|
Accuracy (%)
|
Precision (%)
|
Compiled values
|
Measured (N = 5)
|
Accuracy (%)
|
Precision (%)
|
Major element (wt%):
|
SiO2
|
54.1
|
44.51
|
–17.73
|
5.35
|
49.9
|
39.50
|
–20.85
|
4.52
|
53.20
|
43.27
|
–18.67
|
5.37
|
63.97
|
44.14
|
–31.00
|
6.89
|
TiO2
|
2.26
|
1.74
|
–22.82
|
1.20
|
2.73
|
2.08
|
–23.95
|
0.97
|
1.19
|
0.90
|
–24.33
|
0.98
|
0.85
|
0.49
|
–41.90
|
1.85
|
Al2O3
|
13.5
|
8.16
|
–39.54
|
8.72
|
13.5
|
8.53
|
–36.83
|
8.07
|
14.67
|
9.25
|
–36.92
|
10.97
|
15.22
|
7.52
|
–50.59
|
12.85
|
FeOT
|
12.28
|
10.20
|
–16.95
|
0.18
|
10.95
|
8.30
|
–24.18
|
0.35
|
12.76
|
9.70
|
–24.00
|
0.54
|
6.29
|
5.41
|
–14.01
|
0.42
|
MnO
|
0.2
|
0.22
|
8.30
|
4.52
|
0.17
|
0.19
|
10.89
|
5.33
|
0.20
|
0.21
|
5.00
|
1.80
|
0.157
|
0.17
|
8.28
|
4.86
|
MgO
|
3.59
|
BDL
|
—
|
—
|
7.23
|
4.30
|
–40.53
|
22.32
|
4.66
|
BDL
|
—
|
—
|
1.57
|
BDL
|
—
|
—
|
CaO
|
7.12
|
6.89
|
–3.28
|
0.63
|
11.4
|
10.70
|
–6.14
|
0.68
|
9.89
|
9.81
|
–0.81
|
0.82
|
5.7
|
5.61
|
–1.58
|
1.55
|
Na2O
|
3.16
|
—
|
—
|
—
|
2.22
|
—
|
—
|
—
|
2.03
|
0.35
|
–82.72
|
—
|
3.84
|
—
|
—
|
—
|
K2O
|
1.79
|
1.46
|
–18.44
|
1.23
|
0.52
|
0.44
|
–15.96
|
3.30
|
0.42
|
0.35
|
–16.46
|
2.50
|
0.763
|
0.35
|
–54.13
|
0.95
|
P2O5
|
0.35
|
BDL
|
—
|
—
|
0.27
|
0.17
|
–37.04
|
43.41
|
0.10
|
BDL
|
—
|
—
|
0.165
|
—
|
—
|
—
|
Total:
|
98.35
|
73.18
|
|
|
98.89
|
74.20
|
|
|
99.12
|
|
|
|
98.53
|
63.70
|
|
|
Trace element (ppm):
|
Ba
|
677
|
BDL
|
—
|
—
|
131
|
BDL
|
—
|
—
|
208
|
BDL
|
—
|
—
|
303
|
BDL
|
—
|
—
|
Sr
|
340
|
240
|
–29.41
|
—
|
396
|
275
|
–31
|
2.10
|
178
|
125
|
–30
|
4.62
|
264
|
160
|
–39
|
12.60
|
Zr
|
184.00
|
153
|
–17.12
|
3.28
|
172.00
|
140
|
–19
|
5.83
|
51
|
40
|
–22
|
10.70
|
84
|
72
|
–14
|
6.20
|
V
|
416
|
135
|
–67.55
|
6.01
|
317
|
214
|
–32
|
7.39
|
578
|
788
|
36
|
6.70
|
108
|
270
|
150
|
3.02
|
Cr
|
18.0
|
BDL
|
—
|
—
|
280.0
|
232
|
–17
|
3.28
|
27
|
BDL
|
—
|
—
|
6.4
|
BDL
|
—
|
—
|
Co
|
37
|
BDL
|
|
—
|
45
|
BDL
|
—
|
—
|
39.8
|
BDL
|
—
|
—
|
11
|
BDL
|
—
|
—
|
Ni
|
18
|
BDL
|
—
|
—
|
119
|
92
|
–23
|
19.47
|
14.2
|
BDL
|
—
|
—
|
1.7
|
BDL
|
—
|
—
|
Cu
|
21.0
|
BDL
|
—
|
—
|
127.0
|
118
|
–7
|
8.15
|
227
|
223
|
–2
|
2.25
|
41
|
BDL
|
—
|
—
|
Zn
|
127.0
|
113
|
–11.42
|
8.51
|
103.0
|
90
|
–13
|
8.16
|
110
|
103
|
–7
|
9.34
|
91
|
55
|
–40
|
10.50
|
N = number of measurements on the same spot for each analysis. FeOT = all Fe measured as FeO, BDL = below detection limit, — = not applicable. Compilation data from Govindaraju (1994) and GeoReM (georem.mpch-mainz.gwdg.de; 31 December 2012).
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