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Table T6. Handheld X-ray fluorescence measurements for four certified silicate standards, Expedition 345.

  BCR-2 BHVO-2 JB-2 JA-1
Compiled values Measured (N = 5) Accuracy (%) Precision (%) Compiled values Measured (N = 5) Accuracy (%) Precision (%) Compiled values Measured (N = 5) Accuracy (%) Precision (%) Compiled values Measured (N = 5) Accuracy (%) Precision (%)
Major element (wt%):
SiO2 54.1 44.51 –17.73 5.35 49.9 39.50 –20.85 4.52 53.20 43.27 –18.67 5.37 63.97 44.14 –31.00 6.89
TiO2 2.26 1.74 –22.82 1.20 2.73 2.08 –23.95 0.97 1.19 0.90 –24.33 0.98 0.85 0.49 –41.90 1.85
Al2O3 13.5 8.16 –39.54 8.72 13.5 8.53 –36.83 8.07 14.67 9.25 –36.92 10.97 15.22 7.52 –50.59 12.85
FeOT 12.28 10.20 –16.95 0.18 10.95 8.30 –24.18 0.35 12.76 9.70 –24.00 0.54 6.29 5.41 –14.01 0.42
MnO 0.2 0.22 8.30 4.52 0.17 0.19 10.89 5.33 0.20 0.21 5.00 1.80 0.157 0.17 8.28 4.86
MgO 3.59 BDL 7.23 4.30 –40.53 22.32 4.66 BDL 1.57 BDL
CaO 7.12 6.89 –3.28 0.63 11.4 10.70 –6.14 0.68 9.89 9.81 –0.81 0.82 5.7 5.61 –1.58 1.55
Na2O 3.16 2.22 2.03 0.35 –82.72 3.84
K2O 1.79 1.46 –18.44 1.23 0.52 0.44 –15.96 3.30 0.42 0.35 –16.46 2.50 0.763 0.35 –54.13 0.95
P2O5 0.35 BDL 0.27 0.17 –37.04 43.41 0.10 BDL 0.165
Total: 98.35 73.18     98.89 74.20     99.12       98.53 63.70    
Trace element (ppm):
Ba 677 BDL 131 BDL 208 BDL 303 BDL
Sr 340 240 –29.41 396 275 –31 2.10 178 125 –30 4.62 264 160 –39 12.60
Zr 184.00 153 –17.12 3.28 172.00 140 –19 5.83 51 40 –22 10.70 84 72 –14 6.20
V 416 135 –67.55 6.01 317 214 –32 7.39 578 788 36 6.70 108 270 150 3.02
Cr 18.0 BDL 280.0 232 –17 3.28 27 BDL 6.4 BDL
Co 37 BDL   45 BDL 39.8 BDL 11 BDL
Ni 18 BDL 119 92 –23 19.47 14.2 BDL 1.7 BDL
Cu 21.0 BDL 127.0 118 –7 8.15 227 223 –2 2.25 41 BDL
Zn 127.0 113 –11.42 8.51 103.0 90 –13 8.16 110 103 –7 9.34 91 55 –40 10.50

N = number of measurements on the same spot for each analysis. FeOT = all Fe measured as FeO, BDL = below detection limit, — = not applicable. Compilation data from Govindaraju (1994) and GeoReM (georem.mpch-mainz.gwdg.de; 31 December 2012).

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