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Table T7. Handheld X-ray fluorescence measurements of BCR-2 standard by using rock standard calibration, Expedition 345.
|
Preferred value*
|
Expedition 335
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Expedition 345
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Calibration
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Accuracy (%)
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Calibration (N = 5)
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Precision (%)
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Accuracy (%)
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Major element (wt%):
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SiO2
|
54.1
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48.14
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–11.02
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52.61
|
1.52
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–2.75
|
TiO2
|
2.26
|
1.77
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–21.62
|
2.27
|
0.92
|
0.38
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Al2O3
|
13.5
|
8.9
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–34.07
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9.4
|
6.2
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–30.37
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FeOT
|
12.28
|
12.41
|
1.07
|
12.10
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0.18
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–1.48
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MnO
|
0.2
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0.22
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8.86
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0.19
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1.21
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–5.88
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MgO
|
3.59
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BDL
|
—
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BDL
|
—
|
—
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CaO
|
7.12
|
7.03
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–1.33
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6.77
|
0.87
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–4.92
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Na2O
|
3.16
|
—
|
—
|
—
|
—
|
—
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K2O
|
1.79
|
1.12
|
–37.43
|
0.97
|
3.08
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–45.81
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P2O5
|
0.35
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BDL
|
—
|
BDL
|
—
|
—
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Total:
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98.35
|
|
|
|
|
|
Trace element (ppm):
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Ba
|
677
|
BDL
|
—
|
BDL
|
—
|
—
|
Sr
|
340
|
240
|
–29.41
|
353
|
2.98
|
3.82
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Zr
|
184
|
151
|
–17.80
|
178
|
3.44
|
–3.26
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V
|
416
|
150
|
–63.94
|
535
|
7.49
|
28.61
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Cr
|
18
|
BDL
|
—
|
BDL
|
—
|
—
|
Co
|
37
|
BDL
|
—
|
BDL
|
—
|
—
|
Ni
|
18
|
BDL
|
—
|
BDL
|
—
|
—
|
Cu
|
21
|
BDL
|
—
|
BDL
|
—
|
—
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Zn
|
127
|
105
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–17.32
|
109
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4.43
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–14.17
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* = compilation data from Govindaraju (1994) and GeoReM (georem.mpch-mainz.gwdg.de; 31 December 2012). A spreadsheet from Expedition 335 was also used as another quality control to check measurements. N = number of analyses. FeOT = all Fe as FeO. BDL = below detection limit, — = not applicable.
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