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This research used samples and data provided by the Integrated Ocean Drilling Program (IODP). Funding for this research was provided by the Japan Agency for Marine-Earth Science and Technology (JAMSTEC), the Japan Society for the Promotion of Science (JSPS) KAKENHI (22340129), and the Kochi University Research Project (Research Center for Global Environmental Change by Earth Drilling Sciences). The author is indebted to the staff of the R/V JOIDES Resolution and the Gulf Coast Repository and also gratefully acknowledges the Expedition 320/321 science party. Constructive comments by W. Sager improved the manuscript.