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doi:10.2204/iodp.proc.345.102.2014

Igneous petrology

Rock description procedures during Expedition 345 closely followed those used during IODP Expeditions 335, 304/305, and 309/312 (Expedition 335 Scientists, 2012; Expedition 304/305 Scientists, 2006; Expedition 309/312 Scientists, 2006). These, in turn, were based on Ocean Drilling Program (ODP) Leg 209 and earlier “gabbro” legs (ODP Legs 118, 147, 153, and 176) to maintain a relatively high degree of consistency of description between legs (Shipboard Scientific Party, 1989, 1993a, 1995, 1999a). As during Legs 176, 206, and 209 and Expeditions 304/305 and 309/312, core descriptions were performed by the entire igneous petrology team working together (Shipboard Scientific Party, 2003, 2004). Each member was responsible for one or more aspects of the description (igneous contacts, textures, mineral modes, and habits) and data entry on the entire core to ensure consistency of recorded observations throughout. Commonly, the entire team worked together, particularly when defining units and contacts.

Recovered core was described both macroscopically and microscopically, and its characteristics were entered into the LIMS database through the DESClogik portal. Key information was entered into the Section-unit summary tab in the DESClogik Macroscopic template. This information was then used for the production of VCDs, which summarize the description of each section of core (see “Core descriptions”). The key to symbols used on the VCDs is given in Figure F7.

Piece descriptions and igneous units

Core characterization was based on the description of individual pieces from a recovered section of a core. If neighboring pieces were homogeneous with respect to magmatic features, they were combined to one lithologic interval and accordingly described macroscopically in the corresponding DESClogik tab. Lithologically and texturally similar pieces from consecutive core sections were curated as belonging to the same lithologic interval. The upper and lower ends of each piece were directly taken from the curated piece log available within DESClogik. If within a given piece a contact (e.g., chilled margin, change in primary mineralogy, color, grain size, and structural or textural variation) was recognized, a new lithologic interval was defined and described. In this way, all of the important information about the igneous stratigraphy was preserved on a truly descriptive basis. Where contacts and/or boundaries deviated from horizontal within the core reference frame, their depth was logged at the midpoint on the cut face. A summary of the lithologic intervals, including the description of the igneous contacts, was logged into the corresponding DESClogik tab. The numbering of lithologic intervals started with “1” for each hole and consecutively continued throughout the whole core. Within a given interval, no subdivisions were made. Based on the description of the different lithologic intervals and their contacts, igneous units of coherent rock type were defined on a broader, more interpretative scale after discussions within the whole scientific party. Description, characterization and explanations, and reasons why lithologic intervals were combined into units for each hole separately at the beginning of each igneous hole report. For those cores for which units were defined, tables are presented at beginning of the descriptions of the hole, listing the lithologic intervals in each hole and their classification into units. For each lithologic interval, core-section-interval, interval depth (in mbsf) of top and bottom, piece numbers, a complete lithologic name (name of the principal lithology and modifiers, if used), and a description of the contacts is given. Average grain sizes and modal contents of the principal minerals for individual intervals can be obtained from the VCDs (see “Core descriptions”).

Macroscopic core description

Lithology

Plutonic rock

Plutonic rock was classified on the basis of mineral abundance, grain size, and texture (as inferred prior to alteration) based on the International Union of Geological Sciences (IUGS) system (Streckeisen, 1974; Le Maitre, 1989; Le Maitre et al., 2002). This classification defines the following rock types (Figs. F8, F9):

  • Troctolite: olivine + plagioclase > 95%, olivine > 10%, and plagioclase > 10%.

  • Olivine gabbro: olivine + plagioclase + clinopyroxene, none of which is <5%.

  • Gabbro or diorite: plagioclase + clinopyroxene > 95%, plagioclase > 10%, clinopyroxene > 10%, and quartz < 5%.

  • Gabbronorite: plagioclase + clinopyroxene + orthopyroxene, none of which is <5%.

  • Quartz diorite: quartz 5%–20% of quartz + alkali feldspar + plagioclase (QAP), with alkali feldspar <10% of QAP.

  • Tonalite: quartz 20%–60% of QAP, with alkali feldspar <10% of QAP.

  • Trondhjemite: tonalite with total mafic mineral content <10%.

In the IUGS classification, diorite is distinguished from gabbro by the anorthite content of plagioclase, with diorite having plagioclase containing <50 mol% An and gabbro having plagioclase containing >50 mol% An. Because the anorthite content of was not determined from macroscopic description, we used the following convention: if a gabbroic rock contained quartz (<5%) or primary amphibole (indicating a relatively high degree of fractionation), the rock was classified as diorite. If no quartz or primary amphibole was observed, the rock was classified as gabbro. For plutonic rock rich in chromian spinel, we followed the classification of Leg 209 (Shipboard Scientific Party, 2004): a sample that contains >10% chromian spinel was called chromitite.

We use the rock name “oikocryst gabbro” for troctolite or, less commonly, gabbro containing >40% clinopyroxene oikocrysts. This term describes gabbroic rock characterized by a high concentration of centimeter-scale clinopyroxene oikocrysts, which makes this rock unique and easily recognizable macroscopically. Because of the uniqueness of this rock, we introduced this name to distinguish from normal gabbro, based wholly on the mineral mode, in order to identify oikocryst gabbro in the VCDs and lithology distribution diagrams. For the definition of oikocryst, see below.

Minor modifications to the IUGS system were made to divide the rock types more accurately on the basis of significant differences rather than arbitrary cutoffs based on the abundance of a single mineral. We attempted to follow as closely as possible the descriptions from Leg 209 and Expeditions 304/305, 309/312, and 335 to facilitate intersite comparison.

For gabbroic rock, the following modifiers based on modal mineralogy were used:

  • Disseminated oxide = 1%–2% Fe-Ti oxide.

  • Oxide = >2% Fe-Ti oxide.

  • Olivine bearing = 1%–5% olivine.

  • Orthopyroxene bearing = 1%–5% orthopyroxene.

  • Clinopyroxene bearing = 1%–5% clinopyroxene.

  • Troctolitic = 5%–15% clinopyroxene; >20% olivine.

  • Olivine rich = >70% olivine.

  • Anorthositic = >80% plagioclase.

  • Clinopyroxene oikocryst bearing = 5%–40% clinopyroxene oikocrysts.

Additional descriptive modifiers were defined as

  • Leucocratic: light colored; high proportions of plagioclase.

  • Doleritic: applied to fine- or medium-grained gabbroic rock with dominant ophitic or subophitic textures (Fig. F10).

Volcanic and hypabyssal rock

For volcanic and hypabyssal rock, we used the following definitions:

  • Basalt: all igneous rock of basaltic composition in the size range glassy to fine grained.

  • Dolerite: holocrystalline, fine- to medium-grained rock of basaltic composition with well-developed subophitic or ophitic textures.

  • Olivine dolerite: dolerite with >5% olivine.

In English language usage, the term dolerite is European in origin and functionally equivalent to the North American usage of the term diabase, which is the IODP standard term. However, in Japanese, the term diabase has a distinctly different meaning, referring to strongly altered (green) basaltic rocks and is expressed differently in Kanji script. This usage of “diabase” is also prevalent in Europe. We therefore agreed to use “dolerite.”

Basalt was divided according to phenocryst content, using the following convention:

  • Aphyric = <1% phenocrysts.

  • Sparsely phyric = 1%–5% phenocrysts.

  • Moderately phyric = >5%–10% phenocrysts.

  • Highly phyric = >10% phenocrysts.

If present, phenocryst phase names were used as modifiers in front of the rock name with a hyphen. If <1% phenocrysts, the rock was given the modifier “aphyric.”

Mineralogy

Plutonic rock

In oceanic plutonic rock, the primary rock-forming minerals are olivine, plagioclase, clinopyroxene, orthopyroxene, amphibole, Fe-Ti oxide, sulfides, and rarely quartz. The following data were recorded in the LIMS database for each primary silicate:

  • Visually estimated modal percent, which in fresh rock represents the modal mineralogy as observed; in (partially) altered rock, this represents the estimated igneous modes prior to alteration. Where a mineral occurs in trace quantities (i.e., too low to assign a meaningful percentage), 0.1% was recorded. Accessory phases are also noted where observed. Modal estimates were made independently for each phase by a different team member and summed. If the total deviated significantly from 100%, the interval was reexamined by the team and estimates were adjusted. Where totals were close to 100%, the mode of the most abundant mineral (generally plagioclase) was adjusted, retaining the original estimates of phases that occur in minor abundance (generally oxides, olivine, and/or orthopyroxene). The rationale behind this procedure was that the absolute uncertainty in estimating modal proportions is largest for the most abundant minerals;

  • Minimum, median, and maximum grain size for each mineral phase;

  • Mineral shape: euhedral, euhedral-subhedral, subhedral, subhedral-anhedral, and anhedral; and

  • Mineral habit: equant (aspect ratio < 1:2), subequant (aspect ratio = 1:2 to 1:3), tabular (aspect ratio > 1:3 to 1:5), and elongate (aspect ratio > 1:5), as well as many additional terms often specific for the different habits of individual minerals (e.g., interstitial, poikilitic, acicular, lath-shaped, fibrous, flaky, skeletal, columnar; for more terms used see Shelley, 1993), were used.

Some troctolite and lesser gabbro contains spectacular clinopyroxene oikocrysts. These oikocrysts are a macroscopic feature with a distinctive texture clearly observable in the core. The oikocrysts have a well-defined spherical or augen-like habit that shows a clear boundary to the troctolitic or, less commonly, gabbroic matrix. Chadacrysts (enclosed grains) within the oikocrysts are clearly visible and typically are plagioclase. Olivine only occurs at the outermost rim. Because of their well-defined habit and clear relationships with other minerals, the oikocrysts are easily identified with the naked eye. Clinopyroxene is defined as poikilitic if characterized by interstitial with the matrix. Poikilitic clinopyroxene grains are often very irregular in shape, forming large irregular clusters, with much less defined contact relations relative to the matrix. In more olivine rich gabbros, these clinopyroxenes also include olivine as chadacryst, irrespective of whether they are located in the central part or in the rim of the clinopyroxene. The macroscopic observations concerning the oikocrysts are consistent with microscopic observations.

Volcanic rock

In volcanic and hypabyssal rock, the groundmass, phenocrysts (if any), and vesicles were described. For the groundmass, grain size was recorded using the following definitions:

  • Glassy.

  • Cryptocrystalline = <0.1 mm.

  • Microcrystalline = 0.1–0.2 mm.

  • Fine grained = >0.2–1 mm.

  • Medium grained = >1–5 mm.

  • Coarse grained = >5–30 mm.

For phenocrysts, the abundance (in percent); maximum, minimum, and median grain size (in millimeters); and shape were recorded for each phase. Phenocrysts and groundmass crystals were described based on the identification of phenocrysts in hand sample following the criteria listed below:

  • Aphyric = <1% phenocrysts.

  • Sparsely phyric = 1%–5% phenocrysts.

  • Moderately phyric = 5%–10% phenocrysts.

  • Highly phyric = >10% phenocrysts.

Rock names were further classified by types of phenocrysts present (e.g., sparsely plagioclase-olivine phyric, in which the amount of olivine exceeds the amount of plagioclase).

For vesicles, abundance (in percent); vesicularity; size distribution; minimum, maximum, and modal size (in millimeters); roundness (rounded, subrounded, or well rounded); sphericity (highly spherical, moderately spherical, or slightly spherical or elongate); filling (in percent); and fill composition were documented. If vesicles are elongate, the direction was noted.

Contacts

For igneous contacts between units, the type, definition, geometry, and interpretation were described. We noted when the contact was not recovered. For more details on contacts see “Structural geology.”

Contact types include

  • Grain size contact: units on either side have markedly different grain sizes,

  • Modal contact: units on either side have markedly different mineral proportions, and

  • Color contact: units on either side have markedly different primary (i.e., not alteration related) color.

If contacts were characterized by combinations of the above parameters, the terms were combined (e.g., grain size and modal contact).

Where contacts are obscured by deformation and/or metamorphism, they were called

  • Sheared: if an interval with deformation fabric is in contact with an undeformed interval,

  • Foliated: if both intervals have deformation fabrics, or

  • Tectonic: if the contact appears to be the result of faulting.

Contact definitions describe how well defined a contact is, using the terms sharp, gradational, and sutured. “Sutured” refers to contacts in which individual mineral grains interlock across the contact. Contact geometry can be planar, curved, or irregular.

Following description, contacts were interpreted as being extrusive, intrusive, or igneous. The latter term is used for contacts in plutonic rocks where the lithologies on either side of the contact were interpreted to form part of the same igneous sequence (e.g., a modal contact between cumulate layers or a grain size contact in a graded sequence).

The term “dike” refers to any sharp, well-defined, and relatively thick (>1 cm) crosscutting feature formed by injection of magma. This contrasts with “igneous vein,” which describes a thin (<1 cm) crosscutting feature formed by injection of magma with generally less well defined contacts. Dikes and veins are generally designated as individual intervals.

Texture

Plutonic rock

Textures were defined on the basis of three categories: grain size, grain size distribution, and the relationships between different grains.

Grain sizes were defined as

  • Less than fine grained = < 0.2 mm.

  • Fine grained = >0.2–1 mm.

  • Medium grained = >1–5 mm.

  • Coarse grained = >5–30 mm.

  • Pegmatitic = >30 mm.

For plutonic rock, grain size distributions (Fig. F10) were classed as

  • Equigranular: all minerals are of similar size,

  • Inequigranular: two populations of grain sizes occur, or

  • Seriate: a continuous range of crystal sizes.

For defining textures, we used the terms

  • Granular: aggregation of grains of approximately equal size;

  • Subophitic: partial inclusion of plagioclase in clinopyroxene;

  • Ophitic: total inclusion of plagioclase in clinopyroxene;

  • Comb structure: comb-like arrangement of crystals growing inward from a contact;

  • Dendritic: branching arrangement of elongate crystals;

  • Poikilitic: relatively large oikocrysts enclosing smaller crystals, termed chadacrysts, of one or more other minerals; and

  • Varitextured: domains with contrasting grain size are present.

Similar to the silicate minerals, the textures of oxide and sulfide minerals are described in terms of grain size and their relationship to adjacent minerals. In plutonic rock, oxides commonly occur as aggregates, and for grain size determination, an aggregate is counted as a single grain.

Layering, where present, is divided into modal layering and grain size layering; when neither term describes the observations well, the term “layering (other)” is used and the nature of layering is described in the comments. If layering is present, the geometry of layering is described in the comments (e.g., sharp, gradational, or irregular). For more details see also “Structural geology.”

Volcanic rock

Textures were defined on the basis of three categories: grain size, grain size distribution, and the relationships between different grains.

Grain sizes were defined as follows:

  • Less than fine grained = < 0.2 mm.

  • Fine grained = >0.2–1 mm.

  • Medium grained = >1–5 mm.

For volcanic rock, grain size distribution applies to phenocrysts only, using the terms “unimodal” when all phenocrysts are of similar size, “bimodal” when two size populations are defined, or “seriate” when they form a continuous range of sizes.

The following terms were used to describe the textural relationships between different silicate grains (Fig. F10):

  • Phaneritic: phenocrysts are observable in hand sample and with the naked eye.

  • Aphanitic: phenocrysts are not observable in hand sample but are observable under the microscope.

  • Porphyritic: discrete isolated crystals (phenocrysts) are present in a groundmass of finer grain size.

  • Aphyric: no phenocrysts were observable in hand sample or under the microscope.

  • Intergranular: coarser grains (typically plagioclase) form a touching framework of the rock with interstices filled by crystalline material.

  • Intersertal: coarser touching grains form a framework of the rock with interstices filled by glass.

  • Subophitic: partial inclusion of plagioclase in clinopyroxene.

  • Ophitic: total inclusion of plagioclase in clinopyroxene.

  • Comb structure: comb-like arrangement of crystals growing inward from a contact.

  • Dendritic: branching arrangement of elongate crystals.

Similar to the silicate minerals, the textures of oxide and sulfide minerals were described in terms of grain size and their relationship to adjacent minerals.

Thin section descriptions

Each thin section was photographed in both plane light and under crossed polars (see thin section images in WEBIMAGE in “Supplementary material”). Thin section descriptions closely follow the procedure for macroscopic core description. Where a thin section contained areas with different primary (i.e., not alteration related) lithology, mineralogy, and/or texture, these were defined as domains (e.g., Domain 1, Domain 2, etc.). For thin sections with multiple igneous domains, a map of the domains is shown in the full thin section photomicrograph (Fig. F11), with different domains described separately and their relative abundance noted. For each hole, a table is provided listing the corresponding thin sections, the number and nature of the individual domains, the characteristics of the contact between the domains, and a link to the corresponding image of the thin section with the domain boundaries marked.

The following data were recorded and entered into the LIMS database through separate tabs within the thin section workbook in DESClogik.

Lithology and texture

The following definitions were used for plutonic, volcanic, and ultramafic rock:

  • Rock name (based on thin section observations), using the same definitions as those for macroscopic descriptions;

  • A comment for the whole rock (for all domains);

  • Number of igneous domains within the thin section;

  • Nature of igneous domains, if any (e.g., contact between two units, mix of two lithologies in one section, or presence of texturally different regions within one thin section);

  • Igneous domain relative abundance (in percent);

  • Igneous domain number within the thin section (igneous Domain 1, igneous Domain 2, igneous Domain 3, etc.); this parameter identifies each domain described in the Mineralogy tab;

  • Igneous domain lithology name; if only one domain is present, this is identical to the rock name;

  • Igneous domain grain size modal name (aphanitic, cryptocrystalline, microcrystalline, fine grained, medium grained, coarse grained, and pegmatitic); and

  • Igneous domain comment.

Textural definitions were used for the three different rock types (plutonic, volcanic, and ultramafic) individually, as outlined in the following sections.

Plutonic rock

For the domain grain size distribution in plutonic rock, we used the terms equigranular and seriate. For the description of the texture of each domain, the terms granular, subophitic, ophitic, granophyric, and poikilitic were used.

Volcanic rock

For the textures in volcanic rock, we followed the definitions from Expedition 309/312 (Expedition 309/312 Scientists, 2006).

Volcanic rock is described as holohyaline (100% glass) to holocrystalline (100% crystals). The terms “phyric” and “glomeroporphyritic” indicate the presence of phenocrysts and clusters of phenocrysts, respectively. For a continuous range in grain size, the texture is seriate. In cases where there is no significant grain size difference between groundmass crystals and somewhat larger and more euhedral crystals, which do not adhere to the definition of phenocrysts, the term “microphenocryst” is used. In holohyaline to hypohyaline rock, glass was divided into four distinct types:

  1. Fresh glass (amber in transmitted polarized light and isotropic under crossed polars, commonly found in the outermost parts of preserved chilled margins,

  2. Dark (because of abundant crystallites) interstitial volcanic glass of basaltic composition termed “tachylytic,”

  3. Glass that contains abundant fibrous spherulites, and

  4. Glass that has been altered to clay minerals.

As grain size distribution, the terms equigranular or seriate were used. For groundmass, the following terms were used to describe textures:

  • Intergranular (olivine and pyroxene grains between plagioclase laths),

  • Intersertal (glass between plagioclase laths),

  • Variolitic (fan-like arrangement of divergent microlites),

  • Subophitic (partial inclusion of plagioclase in clinopyroxene), and

  • Ophitic (total inclusion of plagioclase in clinopyroxene).

Flow textures were described as

  • Trachytic (subparallel arrangement of plagioclase laths in the groundmass),

  • Pilotaxitic (aligned plagioclase microlites embedded in a matrix of granular and usually smaller clinopyroxene grains), and

  • Hyalopilitic (aligned plagioclase microlites with glassy matrix).

Mineralogy

Igneous domain mineralogy was described using abundance (in percent) of primary minerals preserved; estimated abundance (in percent) of primary minerals prior to alteration; computed value of mineral replacement by alteration; minimum, maximum, and median size; shape; habit; and special features of primary minerals, using the same conventions as during macroscopic description; individual comments for primary minerals; and absorption colors/pleochroism for clinopyroxene, orthopyroxene, and amphibole.

For plagioclase, a qualifier for zoning was recorded using the following convention:

  • 0 = none.

  • 1 = zoning is rare and weakly developed.

  • 2 = abundant zoning that can range from weak to strong.

  • 3 = nearly ubiquitous, generally strong zoning.

The type of zoning in plagioclase was also documented as

  • Continuous: zoning is optically continuous from core to rim;

  • Discontinuous: zoning occurs from core to rim, but with distinct break(s);

  • Patchy: zoning occurs in patches randomly throughout the grain; and

  • Oscillatory.